About

Celina Balderas Guzmán, PhD, is an Assistant Professor in the Department of Landscape Architecture at the University of Washington. Her research spans environmental planning, design, and science, with a focus on climate adaptation to sea level rise on the coast and urban stormwater inland. On the coast, her work demonstrates specific ways that the climate adaptation actions of humans and adaptation of ecosystems are interdependent, exploring how these interdependencies can be maladaptive by shifting vulnerabilities to other humans or non-humans, or can be synergistic. Using ecological modeling, she has explored these interdependencies focusing on coastal wetlands as nature-based solutions, and her work informs cross-sectoral adaptation planning at a regional scale. Inland, Dr. Balderas studies urban stormwater through a social-ecological lens, investigating the relationship between stormwater pollution and the social, urban form, and land cover characteristics of watersheds through data science and case studies. She has developed new typologies of stormwater wetlands based on lab testing in collaboration with environmental engineers, integrating hydraulic performance, ecological potential, and recreational opportunities into design. Her research has been funded by major institutions such as the National Science Foundation, the National Socio-Environmental Synthesis Center, UC Berkeley, and the MIT Abdul Latif Jameel Water and Food Systems Lab. She holds a PhD in the Department of Landscape Architecture and Environmental Planning from the University of California, Berkeley, and previously obtained master's degrees in urban planning and urban design, as well as an undergraduate degree in architecture, all from MIT.

Research topics

• Organic chemistry
• Environmental chemistry
• Chemistry
• Photochemistry
• Inorganic chemistry

Selected publications

• Seasonal variations in photooxidant formation and light absorption in aqueous extracts of ambient particles

  Atmospheric chemistry and physics · 2024 · 14 citations

  • Chemistry
  • Environmental chemistry
  • Photochemistry

  Abstract. Fog/cloud drops and aerosol liquid water are important sites for the transformations of atmospheric species, largely through reactions with photoformed oxidants such as the hydroxyl radical (⚫OH), singlet molecular oxygen (1O2∗), and oxidizing triplet excited states of organic matter (3C∗). Despite their importance, few studies have measured these oxidants or their seasonal variations. To address this gap, we collected ambient PM2.5 from Davis, California, over the course of a year and measured photooxidant concentrations and light absorption in dilute aqueous extracts. Mass absorption coefficients (MACs) normalized by dissolved organic carbon range from 0.4–3.8 m2 per gram C at 300 nm. Concentrations of ⚫OH, 1O2∗, and 3C∗ in the extracts range from (0.2–4.7) × 10−15 M, (0.7–45) × 10−13 M, and (0.03–7.9) × 10−13 M, respectively, with biomass burning brown carbon playing a major role in light absorption and the formation of 1O2∗ and 3C∗. Extrapolating photooxidant kinetics from our dilute particle extracts to concentrated aerosol liquid water (ALW) conditions gives an estimated ⚫OH concentration of 7 × 10−15 M and ranges for 1O2∗ and 3C∗ of (0.6–7) × 10−12 M and (0.2–1) × 10−12 M, respectively. Compared to the results in Kaur et al. (2019), our ALW predictions show roughly 10 times higher ⚫OH, up to 5 times higher 3C, and 1O2∗ concentrations that are lower by factors of 20–100. These concentrations suggest that 3C∗ and 1O2∗ in ALW dominate the processing of organic compounds that react quickly with these oxidants (e.g., phenols and furans, respectively), while ⚫OH is more important for less reactive organics.

  DOI

• Predicting photooxidant concentrations in aerosol liquid water based on laboratory extracts of ambient particles

  Atmospheric chemistry and physics · 2023 · 25 citations

  • Chemistry
  • Environmental chemistry
  • Organic chemistry

  Abstract. Aerosol liquid water (ALW) is a unique reaction medium, but its chemistry is poorly understood. For example, little is known of photooxidant concentrations – including hydroxyl radicals (⚫OH), singlet molecular oxygen (1O2*), and oxidizing triplet excited states of organic matter (3C*) – even though they likely drive much of ALW chemistry. Due to the very limited water content of particles, it is difficult to quantify oxidant concentrations in ALW directly. To predict these values, we measured photooxidant concentrations in illuminated aqueous particle extracts as a function of dilution and used the resulting oxidant kinetics to extrapolate to ALW conditions. We prepared dilution series from two sets of particles collected in Davis, California: one from winter (WIN) and one from summer (SUM). Both periods are influenced by biomass burning, with dissolved organic carbon (DOC) in the extracts ranging from 10 to 495 mg C L−1. In the winter sample, the ⚫OH concentration is independent of particle mass concentration, with an average value of 5.0 (± 2.2) × 10−15 M, while in summer ⚫OH increases with DOC in the range (0.4–7.7) × 10−15 M. In both winter and summer samples, 3C* concentrations increase rapidly with particle mass concentrations in the extracts and then plateau under more concentrated conditions, with a range of (0.2–7) × 10−13 M. WIN and SUM have the same range of 1O2* concentrations, (0.2–8.5) × 10−12 M, but in WIN the 1O2* concentration increases linearly with DOC, while in SUM 1O2* approaches a plateau. We next extrapolated the relationships of oxidant formation rates and sinks as a function of particle mass concentration from our dilute extracts to the much more concentrated condition of aerosol liquid water. Predicted ⚫OH concentrations in ALW (including mass transport of ⚫OH from the gas phase) are (5–8) × 10−15 M, similar to those in fog/cloud waters. In contrast, predicted concentrations of 3C* and 1O2* in ALW are approximately 10 to 100 times higher than in cloud/fogs, with values of (4–9) × 10−13 M and (1–5) × 10−12 M, respectively. Although ⚫OH is often considered the main sink for organic compounds in the atmospheric aqueous phase, the much higher concentrations of 3C* and 1O2* in aerosol liquid water suggest these photooxidants will be more important sinks for many organics in particle water.

  DOI

• Kinetics and Mass Yields of Aqueous Secondary Organic Aerosol from Highly Substituted Phenols Reacting with a Triplet Excited State

  Environmental Science & Technology · 2021 · 104 citations

  • Chemistry
  • Photochemistry
  • Environmental chemistry

  C* typically the dominant oxidant.

  DOI

Frequent coauthors

• Reed Worland

  22 shared

• Cort Anastasio

  University of California, Davis

  16 shared

• Lan Ma

  University of California, Davis

  12 shared

• Christopher Niedek

  11 shared

• Qi Zhang

  11 shared

• Wenqing Jiang

  10 shared

• Keith J. Bein

  Quality Research

  10 shared

• Camille Mavis

  9 shared

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