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Alice Kunin

Alice Kunin

Princeton University · Chemistry

Active 1982–2026

h-index47
Citations9.6k
Papers3679 last 5y
Funding

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About

Alice Kunin is an Assistant Professor of Chemistry at Princeton University, specializing in spectroscopy and physical chemistry. Her research focuses on using ultrafast spectroscopy to resolve fundamental light-induced processes in condensed phase systems, aiming to understand how electron, hole, and quasiparticle dynamics at surfaces and interfaces evolve on femtosecond to picosecond timescales. Her work investigates exciton dynamics in two-dimensional quantum materials, charge-transfer processes at organic-inorganic interfaces, and photochemistry of heterogeneous photocatalytic reactions on surfaces. These studies are crucial for advancing optoelectronic devices, photovoltaics, solar cells, and environmental surface science. Kunin's lab develops and applies advanced spectroscopic techniques, including pump-probe spectroscopy and time-and-angle-resolved photoemission spectroscopy (tr-ARPES) with momentum microscopy, to image ultrafast charge carrier dynamics. Her technical approach involves high power frequency comb lasers and nonlinear optical methods, such as high harmonic generation for extreme ultraviolet pulses. Her research aims to address gaps in understanding the fundamental electronic behavior of promising photocatalytic and photovoltaic systems, with the goal of enabling precise control over light-matter interactions in these materials.

Research topics

  • Physics
  • Particle physics
  • Nuclear physics
  • Atomic physics
  • Materials science

Selected publications

  • Cavity-enhanced high-order harmonic generation for high-performance time-resolved photoemission experiments

    APL Photonics · 2025-01-01 · 7 citations

    articleOpen access

    Recent breakthroughs in high repetition-rate extreme ultraviolet (XUV) light sources and photoelectron analyzers have led to dramatic advances in the performance of time-resolved photoemission experiments. In this perspective article, we discuss the application of cavity-enhanced high-order harmonic generation, with repetition rates exceeding 10 MHz, to photoemission experiments using advanced endstations incorporating time-of-flight photoelectron analyzers. We discuss recent results, perspectiv…

  • Moiré-controllable exciton localization and dynamics through spatially-modulated inter- and intralayer excitons in a MoSe2/WS2 heterobilayer

    Nature Communications · 2025-12-11 · 2 citations

    articleOpen access

    Moiré heterobilayers exhibiting spatially varying exciton localization that can be precisely controlled through the twist angle have emerged as exciting platforms for studying complex quantum phenomena. Here, we study the exciton landscape in MoSe2/WS2 heterobilayers through synergistic first-principles GW plus Bethe Salpeter equation (GW-BSE) calculations and complementary time- and angle-resolved photoemission spectroscopy (tr-ARPES). We find that the MoSe2/WS2 heterobilayer has a type I band…

  • Momentum-Resolved Exciton Coupling and Valley Polarization Dynamics in Monolayer WS$_2$

    arXiv (Cornell University) · 2022-03-04 · 2 citations

    preprintOpen access1st authorCorresponding

    Coupling between exciton states across the Brillouin zone in monolayer transition metal dichalcogenides can lead to ultrafast valley depolarization. Using time- and angle-resolved photoemission, we present momentum- and energy-resolved measurements of exciton coupling in monolayer WS$_2$. By comparing full 4D ($k_x, k_y, E, t$) data sets after both linearly and circularly polarized excitation, we are able to disentangle intervalley and intravalley exciton coupling dynamics. Recording in the exci…

  • Ultrafast dynamics in 2D materials and heterostructures visualized with time- and angle-resolved photoemission

    2024-03-08 · 1 citations

    articleSenior author

    The optical and electronic properties of two-dimensional (2D) materials make them attractive for a variety of applications in quantum information processing, solar-energy harvesting, and catalysis. However, the dynamics of electrons, holes, and excitons formed after photo-excitation are often complex and involve many states that are optically dark, making their characterization with optical spectroscopy alone difficult. We present our recent work imaging the quantum states of 2D materials and th…

  • Cavity-Enhanced High-order Harmonic Generation for High-Performance Time-resolved Photoemission Experiments

    arXiv (Cornell University) · 2024-10-15 · 1 citations

    preprintOpen access

    Recent breakthroughs in high repetition-rate extreme ultraviolet (XUV) light sources and photoelectron analyzers have led to dramatic advances in the performance of time-resolved photoemission experiments. In this perspective article, we discuss the application of cavity-enhanced high-order harmonic generation (CE-HHG), with repetition rates exceeding 10 MHz, to photoemission experiments using advanced endstations incorporating time-of-flight photoelectron analyzers. We discuss recent results, p…

Frequent coauthors

  • Sw. Banerjee

    636 shared
  • A.A. Vorobyov

    532 shared
  • W. Lohmann

    529 shared
  • J.J. Blaising

    Laboratoire d’Annecy de Physique des Particules

    516 shared
  • Lyndon Jones

    University of Waterloo

    516 shared
  • F. Linde

    508 shared
  • W.J. Metzger

    489 shared
  • K.L. Tung

    451 shared

Labs

  • Kunin LabPI

Education

  • Ph.D., Chemistry

    University of California Berkeley

    2019
  • B.S., Chemistry

    University of Maryland, College Park

    2014

Awards & honors

  • DOD National Defense Science and Engineering Graduate Fellow…
  • Spectroscopy / Physical Chemistry Alice Kunin named a Beckma…

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